Product ID:IMRON POLYURETHANE ACTIVATORS & CLEARS, VGY
MSDS Date:06/15/1988
FSC:8010
NIIN:00N016477
MSDS Number: BKRXR

E I DU PONT DE NEMOURS & CO INC

1007 MARKET STREET
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Cage: B0589

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

ALL THE GROUPS EXPERIENCED EXCURSIONS ABOVE THE

RTECS: 9999999ZZ

POLYURETHANE RESIN.

CAS: 9040-80-6

DEACTIVATE ISOCYANATE CONTAINING SPILLS W/20%

RTECS: 9999999ZZ

0-10% AMMONIA, 2-5% DETERGENT, BALANCE WATER. POUR

RTECS: 9999999ZZ

DO NOT SEAL WASTE CONTAINERS FOR 48 HOURS TO ALLOW

RTECS: 9999999ZZ

MSHA TC-23C) CAN BE USED PROVIDED THE WEARER HAS

RTECS: 9999999ZZ

MFR'S DIRECTIONS FOR RESP USE. INDIVIDUALS

RTECS: 9999999ZZ

SHOULD NOT USE OR BE EXPOSED TO THIS PRODUCT. DO

RTECS: 9999999ZZ

HAVE CAUSED EMBRYOTOXIC EFTS IN LAB ANIMALS.

RTECS: 9999999ZZ

BE ABSORBED THRU SKIN IN HARMFUL AMT. TOLUENE

RTECS: 9999999ZZ

W/COUGH, DFCLT BRTHG, OR SHORTNESS OF BREATH.

RTECS: 9999999ZZ

WHEEZING, COUGH, OR PERM LUNG SENSIT. THIS EFT MAY

RTECS: 9999999ZZ

CNTCT MAY CAUSE CHEM BURNS. LIQ SPLASHES IN THE EYE

RTECS: 9999999ZZ

TDI MFG PLANT HAS RPTD THAT CERTAIN WORKERS EXPOS

RTECS: 9999999ZZ

FUNCT (OVER THE 5 YR PERIOD OF STUDY) THAN OTHER

RTECS: 9999999ZZ

ETHYL ACETATE (SARA III)

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)

CAS: 584-84-9

RTECS: CZ6300000

OSHA PEL C,0.02 PPM/0.02 STEL

ACGIH TLV: 0.005PPM/0.02STEL;93

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:GENL EFTS: INGEST: GI DISTRESS. INHAL:
MAY CAUSE NOSE/THROAT IRRIT. RPTD/PRLNG OVEREXP TO SOLV MAY LEAD TO
PERM BRAIN/NERVS SYS DMG. EYE WATERING/HDCH/NAUS/DIZZ/LOSS OF COORD
ARE SIGNS THAT SOLV LEVEL S ARE TOO HIGH. EXPOS TO ISOCYANATES MAY
CAUSE ASTHMA-LIKE RXNS W/SHORTNESS OF BREATH, WHEEZING, (SEE EFTS
OF OVEREXP)
Explanation of Carcinogenicity:TOLUENE DIISOCYANATE: IARC, GROUP 2B,
NTP GROUP 2.
Effects of Overexposure:HLTH HAZ: COUGH/LUNG SENSIT. EFT MAY BE DELAYED
FOR SEVERAL HRS AFTER EXPOS. INDIVIDUALS W/LUNG OR BRTHG PROB OR
PRIOR RXN TO ISOCYANATES MUST NOT BE EXPOS TO VAPS/SPRAY MIST. EYE:
MAY CAUSE IRRIT/BUR NING. SKIN: RPTD/PRLNG LIQ CNTCT MAY CAUSE
IRRIT W/DISCOMFORT & DERM. SPECIFIC EFTS: ETHYL ACETATE: (SEE SUPP
DATA)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING LUNG
DISEASES, ASTHMA OR BREATHING DIFFICULTIES MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:INGEST: CALL MD IMMEDIATELY AND HAVE NAMES OF INGREDIENTS
AVAILABLE. INHAL: IF BY VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR.
IF BREATHING DIFFICULTY PERSISTS, OR OCCURS LATER, CONSULT MD. EYE:
IMMEDIAT ELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES;
CALL MD. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION OCCURS,
CONTACT MD.

Flash Point Method:CC
Flash Point:<73F,<23C
Lower Limits:0.9%
Upper Limits:13.1%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT RECOMMENDED. WATER FROM FOG NOZZLES MAY BE USED TO COOL
CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS
FLAMM VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE
MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW THE FLASH POINT.

Spill Release Procedures:VENT AREA. REMOVE IGNITION SOURCES. PVNT SKIN
CNTCT & BRTHG VAP. WEAR A POS PRESS SUPPLIED-AIR RESP (NIOSH/MSHA
TC-19C IF POSS, OTHERWISE NIOSH/MSHA TC-23C), EYE PROT, IMPERMEABLE
GLOVES & PROT CLTHG. CONFINE & REMOVE W/INERT ABSORB. (SEE INGRED
06)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE LABEL PREC. KEEP AWAY FROM
HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING
WITHOUT NIOSH/MSHA APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.
DO NOT BREATHE VAPORS OR MISTS. WEAR A RESPIRATOR AT ALL TIMES WHEN
HANDLING ISOCYA NATES/ISOCYANATE ACTIVATED MATERIALS.

Respiratory Protection:WEAR A POS-PRESS, SUPP-AIR RESP (NIOSH/MSHA
TC-19C) DURING SPRAY APPLICATN (OR BRUSH/ROLL APPLICATN IN POORLY
VENTED AREAS). FOR MIXING, BRUSH/ROLL APPLICATN IN WELL-VENTED
AREAS, A NEG-PRESS, VAP/PAR TICULATE RESP (NIOSH/ (SEE INGRED 09)
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:IMPERMEABLE (E.G. NEOPRENE) GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR COVERALLS. DO NOT REUSE WHILE SOLVENT
ODOR IS RETAINED IN THEM.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING & SMOKING. PROT CREAMS MAY BE USED FOR EASE OF CLEAN UP, NOT
FOR PROT.
Supplemental Safety and Health
EFTS OF OVEREXP: PRLNG/RPTD HIGH EXPOS OF LAB ANIMALS RSLTD IN
SECONDARY ANEMIA W/AN INCR IN WHITE BLOOD CELLS, FATTY
DEGENERATION, CLOUDY SWELLING & AN EXCESS OF BLOOD IN VARIOUS
ORGANS. PGMEA: MAY C AUSE MOD EYE BURNING. RECURRENT OVEREXPMAY
RSLT IN LIVER/KIDNEY INJURY. XYLENE: HIGH CONC (SEE INGRED 12)

HCC:F5
Boiling Pt:B.P. Text:170F,77C
Vapor Pres:SEE INGRED
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MOD TO APPRECIABLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:51

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, AMINES.
Stability Condition to Avoid:DO NOT MIX ENAMEL AND ACTIVATOR UNTIL
READY TO USE.
Hazardous Decomposition Products:CO, CO*2, SMOKE.

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.